Polymers inherently have a distribution of chain lengths resulting in a molecular weight distribution. The molecular weight distribution influences the properties of the polymer during processing and in the application. For example, lower molecular weight chains help improve melt processing, while the higher molecular weight fraction can be critical to mechanical properties. A variety of molecular weight analysis techniques specific to material type, industry served, and information required are used at Polymer Solutions (PSI). We will help you choose the one that is right for you.
Solubility of the polymer material to be tested is a critical parameter to be determined when choosing an analytical method for measuring molecular weight.
There are multiple methods for molecular weight determination. The method that provides the most information regarding the molecular weight of a polymer is Gel Permeation Chromatography (GPC), also known as Size Exclusion Chromatography (SEC). GPC/SEC provides you with the molecular weight distribution and depending on the type of calibration will provide you with relative molecular weight values to known standards or absolute molecular weights. This method can be used for determining the level of low molecular weight chains for instance in the range of 1,000 g/mole or less by using a slice table methodology for the calculations.
One of the most broadly useful techniques for comparing or specifying molecular weight limits is Dilute Solution Viscosity (IV). Inherent Viscosity and Intrinsic Viscosity can be used for specification purposes or release purposes but they will not provide you the critical distribution information that may be required in initial research investigations or in full qualification of a material.
In some instances the requirement is to measure a material per a specification which calls for a Melt Flow Index (MFI) value.
Sample submission will depend on the Molecular Weight Analysis technique used.
Contact us to determine the proper technique and associated sample considerations.
Capabilities used to conduct Molecular Weight Analysis: